Brine. Whisk to dissolve the salt (2 tablespoons) in the boiling water (2 cups). Set it aside and allow the water to come to room temp (time saver: place brine in the fridge for 20 minutes). Place pork chops (2) in a resealable bag and pour brine on top. Seal and place in the fridge for 30 minutes - 3 hours.
Season. In a small bowl, combine the seasoning: black pepper (1/4 teaspoon), onion powder (1 teaspoon), garlic powder (1 teaspoon), and cayenne pepper (1/4 teaspoon). Remove pork chops from the brine and discard. Pat the pork chops completely dry and sprinkle seasoning on each side. Press to adhere.
Sear. In a large pan (with a lid) saute the pancetta (4 ounces) until crispy, over medium heat. Use a slotted spoon to set cooked pancetta aside on a paper towel-lined plate, but leave the grease in the pan. Crank the heat of your pan to high. Once wicked hot, add the chops and sear until golden on each side--the time here will depend on your pan/heat, for me, they browned beautifully in 3 minutes on each side. Place seared pork chops aside on a plate.
Sauce. Lower the heat of your pan to medium. Add chicken broth (1/2 cup), and sprinkle xanthan gum (1/8 teaspoon) across the top of the broth. Whisk until it completely dissolves (note 4). Add thyme (1 tablespoon), heavy cream (1/4 cup), and pancetta. Bring your gravy to a simmer.
Simmer. Add the pork chops to the gravy and scoop sauce on top of each. Cover the pan with a lid and allow the pork chops to cook until they come to 145 F in the center (note 5). Start checking after 5 minutes, and every 2 minutes until they come to temp (to prevent overcooking).
Serve pork chops over mashed cauliflower with gravy spooned on top. Enjoy!